Osaka Kyoiku University Researcher Information
日本語 | English
Curriculum Vitaes
Profile Information
- Affiliation
- Professor, Division of Math, Sciences, and Information Technology in Education, Osaka Kyoiku University
- Degree
- Master(Osaka University)理学修士(大阪大学)Docter(Science)(Osaka University)理学博士(大阪大学)
- Researcher number
- 60207165
- J-GLOBAL ID
- 200901018570513090
- researchmap Member ID
- 1000032180
Major Research Interests
12Research Areas
5Research History
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Apr, 2018 - Present
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Apr, 2017 - Present
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Nov, 2006 - Mar, 2017
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2009 - 2009
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2009 - 2009
Education
2-
Apr, 1986 - Mar, 1988
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Apr, 1980 - Mar, 1984
Committee Memberships
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Apr, 2023 - Present
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Dec, 2008 - Present
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2005
Papers
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Acta Crystallographica Section E Crystallographic Communications, 81(1), Jan 1, 2025The asymmetric unit of the title compound is composed of one host molecule, anti-4-(19 H,59 H-3-aza-1,5(3,9)-dicarbazolacyclooctaphane-3-yl)benzonitrile and one dichloromethane solvate molecule, C36H28N4·CH2Cl2. The host molecule possesses a planar chirality but crystallizes as a racemate in the space group P21/c. It adopts an anti-configuration, in which two carbazole rings are partially overlapped with a parallel orientation. The two carbazole ring systems are slightly bent, and the C atoms at the 3- and 1-positions show the largest deviations from the mean planes. The dihedral angle between two carbazole rings is 9.42 (3)°, forming an intramolecular parallel π–π interaction [Cg...Cg = 3.2755 (9) Å]. In the crystal, the molecules are linked via host–host and host–guest C—H...π interactions, forming chain structures along the a-axis direction. The molecules are linked into a ribbon structure along the c-axis direction by further C—H...π interactions. As a result, The molecules are cross-linked by C—H...π interactions into a three-dimensional network.
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Acta Crystallographica Section E Crystallographic Communications, 80(11) 1175-1179, Oct 15, 2024The title compound, [Zn2(C22H18ClN4O)Cl3], is a dinuclear zinc(II) complex with three chlorido ligands and one pentadentate ligand containing quinolin-8-olato and bis(pyridin-2-ylmethyl)amine groups. One of the two ZnII atom adopts a tetrahedral geometry and coordinates two chlorido ligands with chelate coordination of the N and O atoms of the quinolin-8-olato group in the ligand. The other ZnII atom adopts a distorted trigonal–bipyramidal geometry, and coordinates one chlorido-O atom of the quinolin-8-olato group and three N atoms of the bis(pyridin-2-ylmethyl)amine unit. In the crystal, two molecules are associated through a pair of intermolecular C—H...Cl hydrogen bonds, forming a dimer with an R 2 2(12) ring motif. Another intermolecular C—H...Cl hydrogen bond forms a spiral C(8) chain running parallel to the [010] direction. The dimers are linked by these two intermolecular C—H...Cl hydrogen bonds, generating a ribbon sheet structure in ac plane. Two other intermolecular C—H...Cl hydrogen bonds form a C(7) chain along the c-axis direction and another C(7) chain generated by a d-glide plane. The molecules are cross-linked through the four intermolecular C—H...Cl hydrogen bonds to form a three-dimensional network.
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Chemistry Letters, 52(11) 858-860, Nov 5, 2023 Peer-reviewedLead author
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Acta Crystallographica Section E Crystallographic Communications, 79(8) 726-729, Jul 14, 2023 Peer-reviewedIn the title compound, [Na(C22H19N4O4S)(CH3CN)]n, the NaI atom adopts a distorted square-pyramidal coordination geometry, formed by one N and one O atom of the qunolinol moiety in the ligand, two O atoms of sulfonate moieties of two adjacent ligands and the N atom of the coordinated acetonitrile solvent. The NaI atom is located well above the mean basal plane of the square-based pyramid. The apical position is occupied by a sulfonate O atom of a neighboring ligand. Three N atoms of the bis(pyridin-2-ylmethyl)amine moiety in the ligand are not coordinated by the sodium atom. The molecule forms an intramolecular bifurcated O—H...[N(tertiary amine),N(pyridine)] hydrogen bond, generating S(6) and S(5) rings. In the crystal, four molecules are linked by four Na—O(sulfonato) bridged coordination bonds, forming a supramolecular centrosymmetric tetramer unit comprising an eight-membered ring, and generating a two-dimensional network sheet. The molecules of different sheets form intermolecular C—H...O hydrogen bonds, and thereby a three-dimensional network structure.
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Acta Crystallographica Section E Crystallographic Communications, 78(5) 477-480, May 1, 2022 Peer-reviewedCorresponding authorThe title compound, C33H33N3, is a carbazolophane, which is a cyclophane composed of two carbazole fragments. It has a planar chirality but crystallizes as a racemate in the space group P-1. The molecule adopts an anti-configuration, in which two carbazole fragments are partially overlapped. Both carbazole ring systems are slightly bent, with the C atoms at 3-positions showing the largest deviations from the mean planes. The dihedral angle between two carbazole fragments is 5.19 (3)°, allowing an intramolecular slipped π–π interaction [Cg...Cg = 3.2514 (8) Å]. In the crystal, the molecules are linked via intermolecular C—H...N hydrogen bonds and C—H...π interactions into a network sheet parallel to the ab plane. The molecules of different sheets form other C—H...π interactions, thus forming a three-dimensional network.
Misc.
54-
日本化学会春季年会講演予稿集(Web), 103rd, 2023
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基礎有機化学討論会要旨集, 33rd (CD-ROM), 2023
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基礎有機化学討論会要旨集, 32nd (CD-ROM), 2022
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CHEMISTRY LETTERS, 36(3) 460-461, Mar, 2007
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TETRAHEDRON LETTERS, 47(18) 3115-3118, May, 2006
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MOLECULAR PHYSICS, 104(10-11) 1535-1542, May, 2006
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JOURNAL OF PHYSICAL CHEMISTRY B, 109(42) 19681-19687, Oct, 2005
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JOURNAL OF CHEMICAL PHYSICS, 123(8) p084901-1-084901-9, Aug, 2005
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JOURNAL OF PHYSICAL CHEMISTRY B, 108(42) 16457-16462, Oct, 2004
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TETRAHEDRON, 60(30) 6363-6383, Jul, 2004
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POLYMER, 45(8) 2831-2836, Apr, 2004
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BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 77(2) 393-399, Feb, 2004
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CHEMISTRY LETTERS, 32(10) 910-911, Oct, 2003
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JOURNAL OF ORGANIC CHEMISTRY, 67(24) 8706-8709, Nov, 2002
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CHEMISTRY LETTERS, (9) 934-935, Sep, 2002
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JOURNAL OF PHYSICAL CHEMISTRY A, 106(10) 2140-2145, Mar, 2002
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CHEMICAL COMMUNICATIONS, (19) 1914-1915, Oct, 2001
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BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 74(5) 889-906, May, 2001
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JOURNAL OF ORGANIC CHEMISTRY, 65(12) 3708-3715, Jun, 2000
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Bulletin of the Chemical Society of Japan, 73(5) 1259-1275, May, 2000
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Bull. Chem. Soc. Jpn, 73 185-189, 2000 Peer-reviewed
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BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 72(9) 2111-2114, Sep, 1999
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BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 72(8) 1887-1898, Aug, 1999
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TETRAHEDRON LETTERS, 40(25) 4693-4696, Jun, 1999
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SUPRAMOLECULAR CHEMISTRY, 11(1) 83-91, 1999
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JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, (3) 239-246, Feb, 1997
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J. Am. Chem. Soc., 119 1476, 1997 Peer-reviewed
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TETRAHEDRON LETTERS, 36(11) 1883-1886, Mar, 1995
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BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 67(8) 2176-2186, Aug, 1994
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Bull. Chem. Suc. Jpn, 66(4) 1222, 1993 Peer-reviewed
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HETEROCYCLES, 34(8) 1511-1514, Aug, 1992
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Chemistry Express, 7(11) 845-848, 1992 Peer-reviewed
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BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 64(12) 3544-3547, Dec, 1991
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Chem. Lett., 1461-1464, 1991 Peer-reviewed
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Bull. Chem. Soc. Jpn, 64 3544-3547, 1991 Peer-reviewed
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BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 63(10) 2820-2827, Oct, 1990
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Bull. Chem. Soc. Jpn.,, 70 2781-2790, 1990 Peer-reviewed
Books and Other Publications
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Wiley VCH, Apr, 2024 (ISBN: 9783527351800)
Presentations
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International CPL and CPEL Conference 2023 in Osaka, JAPAN, Mar 8, 2023
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International CPL and CPEL Conference 2023 in Osaka, JAPAN, Mar 7, 2023
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International CREST-CPL Conference 2022, Mar 4, 2022 Invited
Teaching Experience
10Research Projects
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日産化学株式会社, Oct, 2023 - Sep, 2024
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触媒科学計測共同研究拠点, 北海道大学触媒科学研究所, Nov, 2023 - Mar, 2024
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令和5 年度国際共同利用・共同研究, 京都大学化学研究所, Apr, 2023 - Mar, 2024
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日産化学株式会社, Oct, 2022 - Sep, 2023