Osaka Kyoiku University Researcher Information
日本語 | English
Curriculum Vitaes
Profile Information
- Affiliation
- Lecturer, Division of Math, Sciences, and Information Technology in Education, Osaka Kyoiku University
- Degree
- 薬学修士(京都大学)Doctor of Pharmaceutical Science(Kyoto University)薬学博士(京都大学)
- Researcher number
- 50200829
- J-GLOBAL ID
- 200901066557434150
- researchmap Member ID
- 6000005610
Research Areas
2Research History
4-
Apr, 2008
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Apr, 2007 - Mar, 2008
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Oct, 1994 - Mar, 2007
Education
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- 1989
Papers
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大阪教育大学紀要. 総合教育科学, 72 335-354, Feb 29, 2024 Peer-reviewedLead authorCorresponding authortype:Article 著者らは,小学校若手教員対象の課題探究型理科研修を毎年実施してきた。2020~21年はコロナ禍によりオンデマンドで実施したが,本稿で論じる2022年の研修では対面形式を再開した。再開した対面研修で,オンデマンドの個人学習用に開発したワークシートを,グループの中での個人の学びの支援のために使用した。同じく個人の振り返り用に開発した探究の流れ図の形式を,グループ活動のまとめポスターに使用した。まとめポスターの評価ルーブリックを開発し,グループ活動を評価した。グループ活動の評価と個人のワークシートの記述から,受講者の学習状況を推測した。併せて,受講者の理科の知識や実験技能の実態について知見を得た。 We have conducted problem-solving and inquiry-based science training for young elementary school teachers every year. In 2020~21, it was conducted on demand due to the corona disaster, but in the 2022 training discussed in this paper, the face-to-face format was resumed. In the resumed face-to-face training, worksheets developed for individual learning in on-demand training were used to support individual learning in groups. The form of the inquiry flow chart,which was also developed for individual reflection, was used as a summary poster for group activities. We developed an evaluation rubric of summary posters and evaluated group activities. From the evaluation of group activities and the description contents of individual worksheets, we estimated learning status of the participants. We also obtained knowledge about the actual state of science knowledge and experimental skills of the participants.
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大阪教育大学紀要. 総合教育科学, 71 349-364, Feb 28, 2023 Peer-reviewedLead authorCorresponding authortype:Article コロナウイルス感染拡大の状況下,小学校若手教員を対象として,探究型理科研修をオンデマンドで実施した。研修実施のため,実験を動画で視聴しながら科学的問題解決の過程を学習するプログラムをGoogle Classroom上に作成した。受講者の到達度評価のためにルーブリックを作成し,評価を試みた。研修の実施と評価から以下の結果を得た。(1)受講者の9割が,オンデマンドプログラムを完全に終了した。(2)3人の評価者による評価の一致度の分析から,ルーブリックの改善のための知見を得た。(3)ルーブリック評価の結果から,科学的問題解決の過程の学びについての受講者の課題が示唆された。(4)水溶液の性質に関する小学校若手教員の知識の現状が明らかになった。 Due to the spread of coronavirus infection, we conducted on-demand teacher training of scientific inquiry activity for young elementary school teachers. To carry out the training, we developed a program on Google Classroom to learn the process of inquiring scientific problems by watching videos of experiments. We also created a rubric to evaluate the achievement of the learners and tried to evaluate it. The following results were obtained from the implementation and evaluation of the training. (1) 90% of the participants have completed the on-demand program. (2) From the analysis of the degree of agreement of the evaluations by the three evaluators, the knowledge for improving the rubric was obtained. (3) The results of the rubric evaluation suggested the young elementary school teachers' challenges in learning the process of solving scientific problems. (4) The current state of knowledge of young elementary school teachers regarding the properties of aqueous solutions has been clarified.
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68 15-30, Feb, 2020 Peer-reviewedLead authorCorresponding author
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BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 89(7) 810-822, Jul, 2016 Peer-reviewedThe first example of abnormal Michael reaction of an active methylene compound, 2-acylmethyl-4,4-dimethyl-2-oxazoline with acetylenic ketone in acetonitrile is reported. The reaction accompanies 1,3-migration of the acyl group of the substrate to give 2-(3-acyl-1-buten-4-on-l-yl)-2-oxazoline, which was easily cyclized to 5-acyl-2-pyridone derivatives by treatment with silica gel. Selectivity of the reaction depends on bulkiness of all the substituents of both the substrate and the reagent. The selectivity is interpreted in terms of reduced kinetic acidity of an initial anionic adduct intermediate by both steric and electronic factors.
Misc.
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Proceedings of the Annual Meeting of Japan Society for Science Education, 45 615-616, 2021
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Proceedings of the Annual Meeting of Japan Society for Science Education, 44 351-354, Aug, 2020 Lead author
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Proceedings of the Annual Meeting of Japan Society for Science Education, 43 632-635, 2019
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Proceedings of the Annual Meeting of Japan Society for Science Education, 42 443-444, 2018
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Proceedings of the Annual Meeting of Japan Society for Science Education, 42 441-442, 2018 Lead author
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Proceedings of the Annual Meeting of Japan Society for Science Education, 41 363-364, 2017 Lead author
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Proceedings of the Annual Meeting of Japan Society for Science Education, 40 249-250, 2016
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大阪教育大学紀要 第3部門 自然科学・応用科学, 61(1) 33-39, Sep, 2012The reaction of (thiepin)iron tricarbonyl(2) with TCNE at room temperature gave the 1,6-adduct(4)in a quantitative yield with none of 1,3-adduct. The structure of 4 was determined by single-crystal X-ray diffraction. The fact is different from that other (cyclicη4-triene)trnsition-metal cmplexes give 1,3-adducts on rection with TCNE. The reaction of 2 with an equimolar amount of TCNE was conducted in CD2Cl2 at -30℃ and followed by 1H NMR spectroscopy. The result of NMR monitoring investigation at a low temperature also excluded intermediative formation of 1,3-adduct. No reaction of (thiepin sulfone)iron tricarbonyl (3) with TCNE occurred. Frontier orbital calculations predict that 1,3-addition is the preferred cycloaddition mode for TCNE to a range of cyclic triene complexes. 1, 6-addition is not an allowed reaction. The sulfur atom of thepin may play an important part in a new mechanism of 1,6-cycloaddition. Oxidative degradation of 4 with ceric ammonium nitrate in ethanol proceeded in 91 % yield to give the free 1,6-adduct (5).
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Tetrahedron, 58(3) 473-478, Jan 14, 2002New methods for functionalization of 1-methyl-2-quinolone (MeQoe) skeleton are provided. The reaction of 1-methyl-3,6,8-trinitro-2-quinolone (TNQ) with amines affords quinolone dimer 1 and 6,8-dinitroquinolone (6,8-DNQ). Dimerization predominantly proceeds at room temperature, and denitration takes place under heated and diluted conditions. We also provide a plausible mechanism for these reactions on the basis of structure-reactivity relationship of amines. © 2002 Elsevier Science Ltd. All rights reserved.
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HETEROCYCLES, 53(3) 543-+, Mar, 2000The reaction of 1-methyl-3,6,8-trinitro-2-quinolone (1) with tertiary amine caused dimerization and denitration. Dimerization predominantly proceeded at room temperature, and denitration mainly occurred under heated conditions.
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Journal of Japan Oil Chemists' Society, 48(9) 897-902, Sep 20, 1999A novel acetylating method using ethyl α-arylacetoacetates was established. Activation of β-keto esters by an aryl group made possible the quantitative transfer of the acetyl group from the keto ester to amines, EtOH and EtSH under mild conditions. The chemoselective acetylation of diamines and aminoalcohols was conducted.<BR>The introduction of an aryl group at the α-position caused various factors to act in concert with good effect, as follows : a) stabilization of the enol form, b) increased acidity of the enol OH group, c) protection of the acetyl group from attack of sterically hindered nucleophiles and d) promotion of the elimination of departing groups by electronic stabilization and steric repulsion.
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JOURNAL OF ORGANIC CHEMISTRY, 64(17) 6476-6478, Aug, 1999
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HETEROCYCLES, 51(3) 567-574, Mar, 19991-Methyl-3,6,8-trinitro-2-quinolone shows high reactivity compared with 1-methyl-3,6-dinitro-2-quinolone. It was found the 8-nitro group activates a 2-quinolone ring sterically rather than electronically.
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JOURNAL OF ORGANIC CHEMISTRY, 64(6) 2160-2162, Mar, 1999
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TETRAHEDRON LETTERS, 39(27) 4851-4852, Jul, 1998Gentle generation of nitrile oxide bearing a carbamoyl group was performed. 4-Nitro-3-isoxazolin-5-one was treated with dipolarophiles in the mixed solvent (MeCN/H2O) at room temperature to afford cycloadducts in good yields. (C) 1998 Elsevier Science Ltd. All rights reserved.
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JOURNAL OF CRYSTAL GROWTH, 146(1-4) 649-654, Jan, 1995Vanadyl-phthalocyanine (VOPc) was found recently to form a pseudomorphic structure on the KBr (001) surface. In order to simulate the initial growth stage, the adsorption energy of molecules of vapor-deposited VOPc was calculated including Van der Waals, electrostatic and induced dipole interactions, in which the charge distribution in a molecule estimated from an ab-initio molecular orbital (MO) calculation was used. The calculation was carried out for the initial growth stage; an adsorbed VOPc molecule on KBr and also a monolayer of VOPc molecules on KBr. The energetically preferred adsorption occurs when the V atom is set directly on the K+ ion and the isoindole ring of VOPc orients almost along [100] of KBr. Such orientation of the molecule agrees well with that determined by structure analysis based on electron crystallography, but not with the adsorption posture proposed so far.
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日本化学会講演予稿集, 68th 107, Sep, 1994
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JOURNAL OF MATERIALS CHEMISTRY, 4(2) 291-297, Feb, 1994Tris(naphthalene-2,3-dioxy)cyclotriphosphazene (TNDOCTP) forms a channel-type clathrate with benzene and also a cage-type one with p-xylene. X-Ray analysis of the p-xylene clathrate showed that the cavity size and form were adequate to accommodate para-disubstituted benzenes into the cage lattice. The extracts obtained from the clathrates which crystallized from a mixture of disubstituted benzenes were analysed by gas chromatography in order to examine the selectivity toward guests by the clathration. TNDOCTP selects most preferentially the para-disubstituted benzenes so that it can isolate para isomers from ortho, meta and para mixtures. The guests that can be included in the cage-type cavity are limited to those having a size and shape similar to that of p-xylene. Among para-substituted toluenes, the host does not recognise the difference among methyl, chloro and bromo groups because of their similarities in size and shape. The crystal grown from an equimolar mixture of p-xylene and benzene is a cage-type p-xylene clathrate and includes only p-xylene, which indicates that the cage-type crystal of TNDOCTP is chosen in preference to the channel-type one. The lattice stability of the former might be preferable to the latter.
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JOURNAL OF ELECTRON MICROSCOPY, 40(4) 273-273, Aug, 1991
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Meeting Abstracts of the Physical Society of Japan, 1991 330-330, 1991
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Proc. of the Int. Con. on the Sci. and Tech. of DefectControl in Semiconductors The Yokohama 21st CenturyForum, 1623-1627, 1990
Books and Other Publications
1Professional Memberships
3-
Sep, 2019 - Present
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Jun, 2016 - Present
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Jun, 2009 - Present
Research Projects
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科学研究費助成事業, 日本学術振興会, Apr, 2024 - Mar, 2027
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科学研究費助成事業, 日本学術振興会, Apr, 2021 - Mar, 2024
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2020 - 2022
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2017 - 2020